Mössbauer Spectroscopy.pdf

Mössbauer Spectroscopy

N. N. Greenwood

Rudolph Mossbauer discovered the phenomenon of recoil-free nuclear resonance fluorescence in 1957-58 and the first indications of hyperfine interactions in a chemical compound were obtained by Kistner and Sunyar in 1960. From these beginnings the technique of Mossbauer spectroscopy rapidly emerged and the astonishing versatility of this new technique soon led to its extensive application to a wide variety of chemical and solid-state problems. This book reviews the results obtained by Mossbauer spectroscopy during the past ten years in the belief that this will provide a firm basis for the continued development and application of the technique to new problems in the future. It has been our aim to write a unified and consistent treatment which firstly presents the basic principles underlying the phenomena involved, then outlines the experimental techniques used, and finally summarises the wealth of experimental and theoretical results which have been obtained. We have tried to give some feeling for the physical basis of the Mossbauer effect with out extensive use of mathematical formalism, and some appreciation of the experimental methods employed without embarking on a detailed discussion of electronics and instrumentation. However, full references to the original literature are provided and particular points can readily be pursued in more detail if required.

The technique of Mössbauer spectroscopy is widely used in mineralogy to examine the valence state of iron, which is found in nature as Fe 0 (metal), Fe 2+, and Fe 3+, as well as the type of coordination polyhedron occupied by iron atoms (trigonal, tetrahedral, octahedral, etc.).It is sometimes used to determine redox ratios in glasses and (less successfully) in rocks. Introduction to Mössbauer Spectroscopy: Part 1

9.54 MB DATEIGRÖSSE
9400956991 ISBN
Englisch SPRACHE
Mössbauer Spectroscopy.pdf

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Mossbauer Spectroscopy - an overview | …

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Welcome to the Mössbauer Effect The Mössbauer Community: Fifty years ago Professor Rudolf L. Mössbauer published a paper in Z. Phys. that initialized a new research area, impacting many segments of the sciences. Research in this area became known as Mössbauer spectroscopy, and has encompassed an …

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4.6: Mössbauer Spectroscopy - Chemistry … The very high sensitivity of the Mössbauer spectrum to the oxidation state and site occupancy of Fe 3+ in cubic inverse spinel iron oxides makes Mössbauer spectroscopy valuable for addressing the issues of whether or not the product of a synthetic method is actually nMag and the extent of B-site vacancy.